If you can find them, unripe grapes of any vitis vinifera persuasion are a tasty additive to stews. They are slightly tart and tannic, but still offer a hint of refreshing sweetness. It's kind of like using verjus. My girlfriend tosses them into a variety of dishes with surprisingly pleasant results. You'd probably have to head to your local Iranian grocer to get them, but they do make for a fun culinary experiment.
Sue's slow cooked pork would have been a great place for them!
As for the cooking wine, I always try to find something white and unoaked for most dishes, but it has to be something I'd enjoy drinking in and of itself ... although I have been known to use Two Buck Chuck in my Hamburger Helper dishes.